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Mixed Conducting Cathodes and Dense Electrolytes for Solid-State Batteries
The first technique improves electrolyte densification, which is essential for ion conductivity and battery reliability overall. The process involves the use of a sintering aid (e.g., sulfur) to achieve denser and more stable electrolytes than are achievable through more common, high-temperature processes. Electrolytes that are denser and less porous have higher ion conductivity (thus better performance), longer cycle lives, and lower volatility. Aside from densification, this technique also significantly increased the base electrolyte's lithium wettability. The second innovation is a new cathode and electrolyte design using a mixed conducting material that can carry both ions and electrons, which simplifies the cathode’s composition by eliminating the need for separate ion and electron conductors. This catholyte is a composite that utilizes a mixed conducting material, replacing both the ion and electron conductors with a single material thus simplifying solid state cathode design from a 3-component to 2-component composite. The mixed material is composed of a metal chalcogenide, such as titanium disulfide (TiS2), which can act as a mixed conductor and contributes to energy storage. The addition of sulfur boosts energy capacity up to 33% compared to traditional cathode designs. Reducing single-conduction phases simplifies energy transport pathways and improves efficiency, making solid-state batteries easier to produce and safer to use. These two innovations work together to improve the state of the art, creating solid-state batteries with higher temperature tolerances and up to five times more energy capacity than current lithium-ion batteries. They stand together at a TRL 4 and are available for patent licensing individually or as part of the larger SABERS (LEW-TOPS-167) or SABERS 2.0 portfolio (LEW-TOPS-188).
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